
1. Introduction to High Chromium Cast Iron Parts
High chromium cast iron is a wear-resistant alloy cast iron characterized by a high chromium content (usually ≥11%). With its ultra-high hardness, excellent wear resistance, and certain corrosion resistance, it has become a material used in mining, cement, power, and other industries to combat severe wear conditions.
Composition and Microstructure
Element |
Typical Content |
Core Function |
Chromium (Cr) |
11-30% |
Forms M₇C₃ type carbides (hardness HV1500-1800), constituting the wear-resistant framework; improves matrix corrosion resistance. |
Carbon (C) |
2.0-3.5% |
Combines with chromium to form carbides; higher content increases wear resistance (but also increases brittleness). |
Molybdenum (Mo) |
0.5-3.0% |
Refines grains, inhibits high-temperature pearlite transformation, and improves hardenability (essential for thick-walled parts). |
Copper (Cu) |
0.5-1.5% |
Replaces molybdenum to reduce cost and enhances corrosion resistance (especially in acidic conditions). |
Nickel (Ni) |
0.5-1.5% |
Stabilizes austenite and improves toughness (synergistic with molybdenum). |
Manganese/Silicon |
≤1.5% |
Deoxidation and flow control; excessive amounts reduce toughness. |
2. Advantages
Wear resistance under rolling: Under abrasive wear conditions, its lifespan is 3-5 times that of high manganese steel and more than twice that of ordinary white cast iron. M₇C₃ carbides have hardness close to corundum sand (Al₂O₃), capable of resisting quartz wear (hardness HV1000-1200).
Corrosion wear resistance: When Cr content ≥20%, corrosion resistance in slurry with pH=3-12 is significantly better than low alloy steel.
High-temperature stability: Hardness does not significantly decrease below 600°C (better than most wear-resistant steels).
3. Key Control Points in Manufacturing Process
1. Casting Process
Melting: Medium-frequency induction furnace + argon deoxidation (reduces slag inclusions).
Pouring: Low temperature and fast pouring (1380-1420°C) to avoid chromium oxidation.
Riser design: Must use insulated risers + exothermic agents to compensate for the shrinkage rate of high chromium iron (≈2.1%).
2. Core Heat Treatment
Stage |
Process Parameters |
Purpose |
Equipment Requirements |
Soft Annealing |
950°C × 4h → furnace cooling to 700°C |
Eliminate casting stress and prepare for machining. |
Controlled atmosphere furnace. |
Quenching |
980-1050°C × 2-4h → air cooling/oil cooling. |
Matrix transforms to martensite to achieve high hardness. |
Precise temperature control (±10°C). |
Tempering |
200-450°C × 4-8h. |
Eliminate quenching stress and adjust toughness. |
Avoid brittleness zone between 450-550°C. |
Warning: Thick-walled parts (>100mm) must use stepped heating (300°C/h), otherwise cracking is inevitable!
4. Typical Application Scenarios and Failure Analysis
Main application fields: High chromium cast iron parts are widely used in mining, cement, power, road construction machinery, refractory materials, and other areas. Since the 1980s, they have been extensively used in the manufacture of shot blasting machine chambers, shot blasting blades, and liners, effectively preventing high-speed dense shot streams from penetrating steel plate shells. They also have broad applications in construction, power, and mining sectors.
Typical application examples: As a highly wear-resistant material, it has been effectively applied in crushing, grinding, material conveying machinery, and metallurgical equipment, especially in parts subject to abrasive and impact wear, such as crusher drums, silo liners, blast furnace bellows, hoppers, coal chute liners, coal mill rollers, rolling bars, and slurry pump flow parts. For example, the high chromium grooved liners installed in early 1988 at Henan Xiangshan Group (formerly Henan Yanshi Cement Plant) operated for 12 years, saving the plant significant costs and reducing the frequency of liner replacements.
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High carbon cast iron parts
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